Bridged dic@ooc~na+r have been syathesixd by the paklhnn-catatymd coupring of distannanes with Lxomacyc1oacbyemployingthcligandstri(2-f~endylsrine. Thccouplingof bnnnacyclooaatetraene wlul termlMi akyne.s is canPared kl coll@ings with alkyuyk3mNumfs forthcpqanuicnof alkylly1cyc1o.
โฆ LIBER โฆ
Synthetic routes to bridged dicyclooctatetraenes and alkynylcyclooctatetraenes
โ Scribed by Siesel, David A.; Staley, Stuart W.
- Book ID
- 121507654
- Publisher
- American Chemical Society
- Year
- 1993
- Tongue
- English
- Weight
- 835 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
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Acylation of the readily available 3-methyl-3-hydroxymethyl oxetane Q leads to the corresponding oxetane esters (3 which rearrange smoothly in the presence of boron trifluoride etherate in methylene chloride at -15" to form ortho esters of the 2,6,7-trioxabicyclo[2.2. aloctane series (2). Protectio