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Synthetic reactions by complex catalysts. VIII. Copper-catalyzed reactions of thiol and alcohol with diazoacetate

โœ Scribed by Saegusa, Takeo; Ito, Yoshihiko; Kobayashi, Shiro; Hirota, Kiwami; Shimizu, Toyoji

Book ID
125495241
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
493 KB
Volume
33
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

Synthetic reaction by complex catalyst I
Synthetic reaction by complex catalyst IV. Copper catalyzed reaction of alcohol with isocyanide
โœ Takeo Saegusa; Yoshihiko Ito; Shiro Kobayashi; Kiwami Hirota ๐Ÿ“‚ Article ๐Ÿ“… 1967 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 178 KB

Recently we have explored a series of copper catalyzed reactions of amine with isocyanide 1) \_ (es. (ill, carbon monoxide 2) (eq. (ii)), diazomethane 3) (en. (iii)), and ethyl diazoacetate 3) (eq. (iv)).

Synthetic reaction by complex catalyst.
Synthetic reaction by complex catalyst. II copper catalyzed carbonylation of amine
โœ Takeo Saegusa; Shiro Kobayashi; Kiwami Hirota; Yoshihiko Ito ๐Ÿ“‚ Article ๐Ÿ“… 1966 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 184 KB

In the preceding communication (l), we have reported that primary and secondary amines react with isocyanide in the presence of copper compound as the catalyst to produce amidines in almost quantitative yields. ## N-R " In view of the fact that carbon monoxide is isoelectronic with isocyanide (2)