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Synthetic Organic Chemistry with Mesoporous Silicas

✍ Scribed by Akichika Itoh; Yukio Masaki


Publisher
John Wiley and Sons
Year
2003
Weight
54 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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Mesoporous Silicas Modified with Dioxomo
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The dioxomolybdenum(VI) fragment MoO 2 X 2 has been confined within the ordered mesopores of pure siliceous hexagonal MCM-41 and cubic MCM-48 molecular sieves either by direct grafting (solvent impregnation) with MoO 2 X 2 (THF) 2 or by using a spacer ligand [L = NC(CH 2 ) 2 Si-(OEt) 3 ]. The materi