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Mesoporous Silicas Modified with Dioxomolybdenum(VI) Complexes: Synthesis and Catalysis

✍ Scribed by Paula Ferreira; Isabel S. Gonçalves; Fritz E. Kühn; André D. Lopes; Manuel A. Martins; Martyn Pillinger; Anabela Pina; João Rocha; Carlos C. Romão; Ana M. Santos; Teresa M. Santos; Anabela A. Valente

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 379 KB
Volume: 2000
Category: Article
ISSN: 1434-1948
DOI: 10.1002/1099-0682(200010)2000:10<2263::aid-ejic2263>3.0.co;2-u

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✦ Synopsis

The dioxomolybdenum(VI) fragment MoO 2 X 2 has been confined within the ordered mesopores of pure siliceous hexagonal MCM-41 and cubic MCM-48 molecular sieves either by direct grafting (solvent impregnation) with MoO 2 X 2 (THF) 2 or by using a spacer ligand [L = NC(CH 2 ) 2 Si-(OEt) 3 ]. The materials have been characterised by elemental [a

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Molecular Structure–Activity Relationships for the Oxidation of Organic Compounds Using Mesoporous Silica Catalysts Derivatised with Bis(halogeno)dioxomolybdenum(VI) Complexes

✍ Carla D. Nunes; Anabela A. Valente; Martyn Pillinger; João Rocha; Isabel S. Gonç 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 297 KB 👁 2 views