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Synthetic disproof against the structure proposed for alectrol, the germination stimulant from Vigna unguiculata

✍ Scribed by Kenji Mori; Junichi Matsui; Masahiko Bando; Masaru Kido; Yasutomo Takeuchi

Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 229 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)01238-6

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✦ Synopsis

Several compounds [(+)-3a, (-+)-3b, (+)-10, (+-)-11 and (+)-12] with the structures related to that (3) proposed for alectrol, the germination stimulant, were synthesized. The structure (+)-3a was solved by X-ray crystallographic analysis. Comparison of the IH NMR data of the synthetic compounds with those reported for alectrol disproved the correctness of the proposed structure 3.

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