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Synthetic chemistry: An upfront investment

✍ Scribed by Young, Damian W

Book ID
109913343
Publisher
Nature Publishing Group
Year
2010
Tongue
English
Weight
152 KB
Volume
6
Category
Article
ISSN
1552-4450

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An upfront investment
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✍ Young, Damian W 📂 Article 📅 2010 🏛 Nature Publishing Group 🌐 English ⚖ 50 KB
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## Abstract A synthesis of 1233A [(2__E__,4__E__,7__R__,2′__R__,3′__R__)‐11‐[3′‐(hydroxymethyl)‐4′‐oxo‐2′‐oxetanyl]‐3,5,7‐trimethyl‐2,4‐undecadienoic acid (1a)] was achieved by employing (__R__)‐2‐hydroxymethyl‐3‐butenyl acetate (2a) and (__R__)‐citronellic acid (3) as chiral building blocks. The f

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## Abstract Both the enantiomers of incrustoporin (2‐__p__‐tolyl‐2‐hexen‐4‐olide, 1) were synthesized by starting from methyl __p__‐tolylacetate (2) and (__S__)‐1,2‐epoxybutane (3). The naturally occurring compound 1 was shown to possess the __R__ configuration.