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Synthetic approaches to 3Fe and 3Fe, Co sites in iron-sulfur proteins

✍ Scribed by E.K.H. Roth; J. Jordanov


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
81 KB
Volume
36
Category
Article
ISSN
0162-0134

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Two nucleophilic allylic organozirconium compounds 9-10 (R 5 : Me and tBu) have been reacted with acyclic isolated h 5 -pentadienyl-Fe(CO) 3 /Fe(CO) 2 PPh 3 (+1) cations or with these intermediates generated in situ (Uemura-like conditions). Depending on reaction conditions, iron-complexed h 4 -dien