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Double exchange in polynuclear mixed-valence clusters. 2. Iron-sulfur proteins [Fe4S4]+and [Fe4S4]3+

✍ Scribed by J. J. Borras-Almenar; R. Jorge; S. I. Klokishner; E. Coronado; S. M. Ostrovskii; A. V. Palii; B. S. Tsukerblat


Publisher
SP MAIK Nauka/Interperiodica
Year
1996
Tongue
English
Weight
539 KB
Volume
37
Category
Article
ISSN
0022-4766

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Single-Crystal 57Fe Q-Band ENDOR Study o
✍ Fabrice Moriaud; Serge Gambarelli; Bernard Lamotte; Jean-Marie Mouesca πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 117 KB

57 Fe Q-band ENDOR has been used to study the [4Fe-4S] 1+ state created by Ξ³ irradiation of single crystals of the synthetic model compound [N(C 2 H 5 ) 4 ] 2 [Fe 4 S 4 (SCH 2 C 6 H 5 ) 4 ] enriched in 57 Fe. This compound is an excellent biomimetic model of the active sites of many 4 iron-4 sulfur