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Origin of the broken-symmetry ground state of mixed-valence [Fe3S4]0 and (Fe4S4]3+ cores in proteins and models

โœ Scribed by E.L. Bominaar; S.A. Borshch; G. Blondin; J.-J. Girerd


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
81 KB
Volume
51
Category
Article
ISSN
0162-0134

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Metal Clusters as Ligands: Substitution of Fe ions in Fe/Mo/S Clusters by Thiophilic Cu I Ions To Give Clusters with [Cu 4 Mo 2 Fe 2 S 8 ] 4+ and [Cu 5 Mo 3 Fe 4 S 11 ] 6+ Cores