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A New Cubane Cluster with the [MoFe3S4]0 Core and Possible Relevance to the Fe3-Centers in Ferredoxins. The Synthesis, Structure and Properties of the [Fe3S4(SEt)3Mo(CO)3]3⊖ Anion

✍ Scribed by Prof. Dr. Dimitri Coucouvanis; Saleem Al-Ahmad; Athanasios Salifoglou; W. Richard Dunham; Richard H. Sands


Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
379 KB
Volume
27
Category
Article
ISSN
0044-8249

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Synthesis and Structure of [Sn4Se11]6–,
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Reaction of A 2 CO 3 (A = K, Rb) with Sn and Se in an H 2 O/CH 3 OH mixture at 115±130 °C affords the isotypic selenidostannates(IV) A 6 Sn 4 Se 11 ´x H 2 O (A = K, x = 8) 1 and 2 whose discrete [Sn 4 Se 11 ] 6± anions each contain two corner-bridged ditetrahedral [Sn 2 Se 6 ] 4± species. Similar re