Synthetic and Structural Studies of PdII and PtII Complexes with Quincorine and Quincoridine Derivatives
✍ Scribed by Manfred Fild; Carsten Thöne; Stefania Tötös
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 273 KB
- Volume
- 2004
- Category
- Article
- ISSN
- 1434-1948
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## Abstract The complexes [PdCl~2~(pap)] (1) and [PtCl~2~(pap)] (2; pap = 2‐phenylazopyridine) were synthesized by treating PdCl~2~ or K~2~PtCl~4~, respectively, with pap and characterized by ^1^H NMR spectroscopy and elemental analysis. Both these complexes, together with the previously reported c
Scheme 1. Phosphorus derivatives of 2,2'-bipyridine.
Reaction of 2-acetylpyridine 4-methylthiosemicarbazone 199 Hg-NMR spectroscopy when relevant, the ligand is N,N,Stridentate, coordinating to the metal centre through its (H4ML) with halides of zinc(II), cadmium(II), and mercury(II) afforded complexes of the form [M(H4ML)X 2 ] [M = Zn II (1-pyridine