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Synthetic and structural studies of methyl- and phenylpalladium(II) complexes of poly(pyrazol-1-yl) borates, and the η3-allylpalladium(II) complex Pd(η3-C3H5){(pz)3BH-N,N′}

✍ Scribed by Allan J. Canty; Hong Jin; Andrew S. Roberts; Peter R. Traill; Brian W. Skelton; Allan H. White


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
584 KB
Volume
489
Category
Article
ISSN
0022-328X

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Structural studies on chiral (π-Allyl)Pd
✍ Paul S. Pregosin; Renzo Salzmann 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 426 KB

## Abstract The chiral (π‐allyl)Pd(II) complex [Pd(η^3^CH~3~CHCHCH~2~)(__S, S__‐Chiraphos)]CF~3~SO~3~ was shown to exist in four isomeric forms (two diastereomeric and two geometric). Aspects of their three‐dimensional structures were elucidated using ^1^H, ^13^C and ^31^P one‐ and two‐dimensional