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Synthetic and structural chemistry of nickel(II) complexes containing dithiolato and phosphine ligands I. Preparation and crystal structure of Ni2(PPh3)2(edt)2

✍ Scribed by Rong Cao; Zhi-Ying Huang; Xin-Jian Lei; Bei-Sheng Kang; Mao-Chun Hong; Han-Qin Liu


Book ID
112060067
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
284 KB
Volume
10
Category
Article
ISSN
0256-7660

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Preparation and Crystal Structures of Ni
✍ A. Leineweber; H. Jacobs 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 243 KB

Diammine nickel(II) halides, Ni(NH 3 ) 2 X 2 (X ‫؍‬ Cl, Br, I), were prepared by decomposition of the corresponding hexaammines at 1203C in dynamical vacuum. Their crystal structures are of the Cd(NH 3 ) 2 Cl 2 type (99 -type::, space group Cmmm, Z ‫؍‬ 2): for Ni(NH 3 ) 2 Cl 2 , a ‫؍‬ 8.019 A s , b