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Syntheses of palladium(II) complexes with thiolate and phosphine ligands. X-ray crystal structures of [Pd(tdt)(PPh3)2] · C2H4Cl2 and [Pd2(Hmp)2(PPh3)Cl2]

✍ Scribed by Rong Cao; Maocuun Hong; Feilong Jiang; Beisheg Kang; Xiulan Xie; Hanqin Liu


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
637 KB
Volume
15
Category
Article
ISSN
0277-5387

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Syntheses and Crystal Structures of [(AM
✍ Bernhard Neumüller; Majid M. Heravi; Mitra Ghassemzadeh 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 115 KB 👁 1 views

The reaction of [(AMTTO)PdCl 2 ] (1) (AMT-TO = 4-Amino-6-methyl-1,2,4-triazine-3(2H)-thione-5-one) with triphenylphosphane and sodium thiocyanate led to the air-stable crystalline complexes [(AMTTO)Pd(PPh 3 )Cl]Cl ḾeOH (2) and [(AMTTO)Pd(SCN) 2 ] ´MeCN (3) in excellent yields. 2 and 3 have been char