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Synthetic and Mechanistic Studies of the Retro-Claisen Rearrangement 4. An Application to the Total Synthesis of (+)-Laurenyne

โœ Scribed by Boeckman,, Robert K.; Zhang, Jing; Reeder, Michael R.


Book ID
126993901
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
109 KB
Volume
4
Category
Article
ISSN
1523-7060

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## Abstract Heating of oxepines and oxacenes of type (I) and (IV) as well as cyclobutanecarboxaldehydes like (VII) with Staudinger reagents is found to provide an efficient approach to medium ring nitrogen heterocycles.