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Synthesis α-aminonitrile through anodic cyanation of N-benzylpiperidine

✍ Scribed by Ping Zhao; Ying-Wu Yin

Publisher: Journal of Heterocyclic Chemistry
Year: 2004
Tongue: English
Weight: 135 KB
Volume: 41
Category: Article
ISSN: 0022-152X
DOI: 10.1002/jhet.5570410204

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✦ Synopsis

Abstract

Six‐membered cyclic α‐aminonitrile has been prepared from anodic cyanation of N‐benzylpiperidine. Good yields of α‐aminonitriles could be obtained through potentiostatic electrolysis under different conditions. The results also explain why high yield α‐aminonitriles could not be obtained under constant current electrolysis.

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