✦ LIBER ✦

Synthesis, X-Ray Structure and Complexation Behavior of the New Tripodal Phosphane Ligandcis, cis-1,3,5-Tris[(diphenylphosphanyl)methyl]1-1,3,5-trimethylcyclohexane (tdppmtmcy). Crystal Structure of Ir(tdppmtmcy)(CO)Cl

✍ Scribed by Mayer, Hermann A. ;Fawzi, Riad ;Steimann, Manfred

Publisher: Wiley (John Wiley & Sons)
Year: 1993
Tongue: English
Weight: 590 KB
Volume: 126
Category: Article
ISSN: 0009-2940
DOI: 10.1002/cber.19931260612

No coin nor oath required. For personal study only.

✦ Synopsis

The introduction of three methyl groups into the ips0 positions analysis) in the solid state. Treatment of 5 with Ir(PPh&(CO)Cl of the cyclohexane ring in cis,cis-l,3,5-tris[(diphenylphos-gives 6 where the two PPh3 groups are replaced by two (diphanyl)methyl]cyclohexane (tdppmcy) (1) leads to the new phenylphosphany1)methyl groups of the ligand 5. In addition, tripodal phosphane ligand cis,cis-1,3,5-tris[(diphenylphos-an intramolecular C-H metalation takes place resulting in the phanyl)methyl]-l,3,5-trimethylcyclohexane (tdppmtmcy) (5). oxidative addition of a ring methylene C-H bond to the metal. The dynamic behavior is studied by variable-temperature NMR spectroscopy and compared with the structure (X-ray The X-ray structure of 6 is determined.

📜 SIMILAR VOLUMES

Syntheses and Characterization of New Co

Syntheses and Characterization of New Copper Complexes with the Heterocyclic Thione, AMTTO. X-Ray Structures of [Cu(AMTTO)Cl2], [Cu(AMTTO)2]Cl, and [Cu(AMTTO)(PPh3)2Cl] (AMTTO = 4-Amino-6-methyl-1, 2, 4-triazine-3-thione-5-one)

✍ Mitra Ghassemzadeh; Forough Adhami; Majid M. Heravi; Abas Taeb; Soheila Chitsaz; 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 134 KB 👁 2 views

Synthesis, Structural Characterisation a

Synthesis, Structural Characterisation and Reactivity of New Dinuclear Monocyclopentadienyl Imidoniobium and -tantalum Complexes − X-ray Crystal Structures of [{Nb(η5-C5H4SiMe3)Cl2}2(μ-1,4-NC6H4N)], [{Ta(η5-C5Me5)Cl2}2(μ-1,4-NC6H4N)] and [{Ta(η5-C5Me5)(CH2SiMe3)2}2(μ-1,4-NC6H4N)]

✍ Antonio Antiñolo; Iván Dorado; Mariano Fajardo; Andrés Garcés; Isabel López-Sol 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 1 views

## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3