Syntheses and Characterization of New Copper Complexes with the Heterocyclic Thione, AMTTO. X-Ray Structures of [Cu(AMTTO)Cl2], [Cu(AMTTO)2]Cl, and [Cu(AMTTO)(PPh3)2Cl] (AMTTO = 4-Amino-6-methyl-1, 2, 4-triazine-3-thione-5-one)

Syntheses of New Sulfur−Nitrogen Pallada

Syntheses of New Sulfur−Nitrogen Palladacycles − Crystal Structures of [(AMTTO)PdBr2]2·3.5THF, [(AMTTO)PdI2]2·3MeOH, [(AMTTO)Pd(PPh3)Br]Br·MeOH, and [(AMTTO)Pd(PPh3)I]·2MeOH (AMTTO = 4-Amino-6-methyl-1,2,4-triazine-3-thione-5-one)

✍ Mitra Ghassemzadeh; Mohammad Bolourtchian; Soheila Chitsaz; Bernhard Neumüller; 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 481 KB

## Reactions of [(AMTTO)PdCl 2 ]•MeOH (1) with sodium bromide and sodium iodide led to the palladacycles [(AMTTO)PdBr 2 ] 2 •3.5THF (2) and [(AMTTO)PdI 2 ] 2 •3MeOH (3) in excellent yields. Treatment of 2 and 3 with triphenylphosphane gave the complexes [(AMTTO)Pd(PPh 3 )Br]-Br•MeOH (4) and [(AMTT