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Synthesis, X-ray Crystal Structures, Magnetism, and Phosphate Ester Cleavage Properties of Copper(II) Complexes of N - Substituted Derivatives of 1,4,7-Triazacyclononane

✍ Scribed by Belousoff, Matthew J.; Duriska, Martin B.; Graham, Bim; Batten, Stuart R.; Moubaraki, Boujemaa; Murray, Keith S.; Spiccia, Leone


Book ID
126223742
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
282 KB
Volume
45
Category
Article
ISSN
0020-1669

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## Abstract The synthesis, X‐ray crystal structure and magnetic properties of two oxalato‐bridged dinuclear Cu^II^ complexes, [L‐Cu(μ‐ox)Cu‐L](ClO~4~)~2~, where ox = oxalate and L = 1,4,7‐trimethyl‐1,4,7‐triazacyclononane (Me~3~tacn) or 1‐benzyl‐4,7‐dimethyl‐1,4,7‐triazacyclononane (BzMe~2~tacn) ar

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## Abstract Two new binucleating ligands, 1,3‐bis[(4,7‐dimethyl‐1,4,7‐triazacyclononan‐1‐yl)methyl]benzene (L^memx^) and 1,2‐bis[(4,7‐dimethyl‐1,4,7‐triazacyclononan‐1‐yl)methyl]benzene(L^meox^), have been prepared from 1,4,7‐triazatricyclo[5.2.1.0^4,10^]decane and applied in the synthesis of the c