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Synthesis, X-ray crystal structure and spectroscopic characterization of heterotrinuclear oxo-centered complex [Fe2NiO(CH3CH2COO)6(H2O)3]

✍ Scribed by Mohammad Yazdanbakhsh; Haman Tavakkoli; Maryam Taherzadeh; Roland Boese


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
664 KB
Volume
982
Category
Article
ISSN
0022-2860

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## Synthesis and X-ray Crystal Structure Analysis of C U ~( C H ~C H ~C O O ) \* ( O P P ~~) ~ The complex of [ C U ( C H ~C H C O O ) ~( O P ~~) ] ~ has been synthesized and its X-ray crystal structure determined at room temperature, M = 975.96, tetragonal, space group: I41/a(#88), Dx = 1.39 g/ c

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The title compound and its potassium analog have been prepared from corresponding aqueous solutions of 9 T c 0 , at p H z 2 with SO2 as a reducing agent. An X-ray structure determination of the Na-salt showed Tc coordinated to the tetradentate N (CH,COO)Z-ligand (NTA). Two Tc-NTA moieties are joined