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Synthesis, Thermal Stability, and Structure of (V.13Mo.87)O2.935: A New Oxide with the Open "Hexagonal MoO3" Structure

✍ Scribed by Yatao Hu; Peter K. Davies


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
772 KB
Volume
105
Category
Article
ISSN
0022-4596

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[Bi12O14E12]nColumns and Lone PairsEin B
✍ RenΓ©e Enjalbert; Georg Hasselmann; Jean Galy πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 412 KB

A new phase, Bi 13 Mo 4 VO 34 E 13 (E: Bi(III) lone pair) was found in the Bi 2 O 3 -MoO 3 -V 2 O 5 system and its formula determined via single crystal analysis and confirmed by solid state synthesis. It crystallizes in the monoclinic system, space group P2/c, with cell parameters a ‫؍‬ 11.652(7) A