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Synthesis, Structures and Reactivity of Group 4 Hydrazido Complexes Supported by Calix[4]arene Ligands

✍ Scribed by Clulow, Andrew J.; Selby, Jonathan D.; Cushion, Michael G.; Schwarz, Andrew D.; Mountford, Philip


Book ID
125972433
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
853 KB
Volume
47
Category
Article
ISSN
0020-1669

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Dinuclear Molybdenum(III) and Tungsten(I
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Addition of p-tert-butylcalix[4]arene LH 4 to the dinuclear ported by two bridging Β΅ 2 -ΞΊ 2 O,ΞΊ 2 O-calix[4]arene ligands in compounds M 2 (NMe 2 ) 6 (M = Mo, W) results in the formation the solid state. These compounds are the first examples of a of [NH 2 Me 2 ] 2 [L 2 M 2 ] 1 (M = Mo) and 2 (M = W