## Abstract **The cover picture shows** the reaction of a calix[4]arene methyl ether stabilized nitridomolybdenum complex [MoN(MeCalix)] with GaCl~3~ to yield the compound [Mo(NGa‐Cl~3~)(MeCalix)]. This complex represents the first structurally characterized example of a nitrido‐bridged dinuclear c
Synthesis, Molecular Structure and Reactivity of a Calix[4]arene Monomethyl Ether Supported Nitridomolybdenum Complex
✍ Scribed by Jürgen Zeller; Susanne Büschel; Benjamin K. H. Reiser; Farida Begum; Udo Radius
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 125 KB
- Volume
- 2005
- Category
- Article
- ISSN
- 1434-1948
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## Abstract New mononuclear titanium complexes [TiCl(Rcalix)] [R = Me (1), Bz (2), SiMe~3~ (3)] supported by __p__‐__tert__‐butylcalix[4]arene mono(organyl)ethers (Rcalix) were prepared in good yield from H~2~R~2~calix and [TiCl~4~(THF)~2~]. The crystallographically characterized complex [TiCl(Meca
The hetero-armedp-(tert -butyl)calix[4]arene 1 was synthesized by a stepwise procedure. This ligand presented a very strong complexing behavior towards Cu', giving the chiral complex 2 and parent species when reacted with Cu" salts. High-resolution NMR techniques were employed for the characterizati