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Synthesis, structure determination, and infrared spectroscopy of (NpO2)2(SO4)(H2O)4: Prevalence of cation–cation interactions and cationic nets in neptunyl sulfate compounds

✍ Scribed by T.Z. Forbes; P.C. Burns


Book ID
104030241
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
487 KB
Volume
182
Category
Article
ISSN
0022-4596

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Cation-Cation Interactions: Crystal Structures of Neptunyl(V) Selenate Hydrates, (NpO2)2(SeO4)(H2O)n (n = 1, 2, and 4). -Green crystals of (NpO2)2(SeO4)(H2O)4 (I), (NpO2)2(SeO4)(H2O)2 (II), and (NpO2)2(SeO4)(H2O) (III) are hydrothermally synthesized from mixtures of Na2SeO4 in 2 M aq. NaOH and in 0.