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Synthesis, Structure, Coordination Expansion and Theoretical Modelling of Dichlorobis(phenoxo) Titanium(IV) Complexes

✍ Scribed by Alastair J. Nielson; Chaohong Shen; Peter Schwerdtfeger; Joyce M. Waters


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
207 KB
Volume
2005
Category
Article
ISSN
1434-1948

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The dichlorodihydridoruthenium (IV) compound [RuH 2 Cl 2 -were obtained. The phenylvinylidene complex [RuCl 2 (=C= CHPh)(PCy 3 ) 2 ] (15) was prepared from phenylacetylene and (PiPr 3 ) 2 ] (4) was prepared from [RuCl 2 (C 8 H 12 )] n (3), PiPr 3 , and H 2 in 2-butanol via the chlorohydridoruthenium