Synthesis, structure, chemistry, and applications of tetravalent nickel complexes
β Scribed by Sivaramakrishna, Akella; Clayton, Hadley S.; Muralikrishna, Upadhyayula
- Book ID
- 111890952
- Publisher
- Taylor and Francis Group
- Year
- 2011
- Tongue
- English
- Weight
- 972 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0095-8972
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New neutral pentacoordinate nickel(II) complexes of the type have been synthesized and characterized both in the solid state and in solution. Interesting X-ray structural data have been collected for each class of compounds, which show, inter alia, that the pentacoordinate neutral complexes can be
## Abstract The complex [Tp^Ph,Me^Ni(Cl)Pz^Ph,Me^H] (**I**) [Tp^Ph,Me^=hydrotris(3βphenylβ5βmethylβpyrazolβ1βyl)borate; Pz^Ph,Me^H=3βphenylβ5βmethylβpyrazole] has been synthesized and explored as ionophore for the preparation of a poly(vinyl chloride) (PVC) membrane sensor for benzoate anions. The