## Abstract Amphiphilic 1,5โdiazaโ3,7โdiphosphacyclooctanes have been synthesized by condensation of hydrophobic primary arylphosphines, formaldehyde, and functionalized hydrophilic primary arylamines (5โaminoisophthalic acid and the sodium salt of sulfanilic acid). These compounds readily form P,P
Synthesis, Structure, and Transition Metal Complexes of Amphiphilic 1,5-Diaza-3,7-diphosphacyclooctanes.
โ Scribed by Andrey A. Karasik; et al. et al.
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 19 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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๐ SIMILAR VOLUMES
Redox reactions in the initial products formed from K~2~[Cr(CO)~5~] and Cl~2~ER (E = Al, Ga; R = Cl, alkyl) lead to the formation of aluminum(I) and gallium(I) transition metal complexes of type 1 (shown below) that are surprisingly stable. Stoichiometric CrGa films were prepared from 1 (E = Ga, R =
5-thiolates / 2-Phenyl-1,2,3,4-tetrazole-5-thiolates / Palladium / Platinum / Copper / Silver / Gold / Molecular structures The molecular structures of nine transition metal tetrazole-Ph 3 PAu(SCN 4 Me) via AuฯชS contacts, leading to dimeric strands in the solid state. The copper compound thiolates h