Synthesis, Structure, and Thermolysis of a 1,5-Dioxa-4.lambda.5-phosphaspiro[3.3]heptane: A Novel Pentacoordinate 1,2-Oxaphosphetane
โ Scribed by Kawashima, Takayuki; Takami, Hiromichi; Okazaki, Renji
- Book ID
- 126988971
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 219 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
The first 1,5-dioxa-4l 4 -telluraspiro[3.3]heptane was synthesized and its structure was determined by X-ray analysis. This tellurane gave the corresponding oxirane and olefin, as well as alcohol, upon heating, which were shown to be formed via a radical pathway.
1,3,2l 5 -Oxazaphosphetidines bearing the Martin ligand were synthesized by the reaction of the corresponding iminophosphorane and carbonyl compounds and characterized by X-ray crystallographic analysis. Thermolysis of the oxazaphosphetidine gave the cyclic phosphinate and the corresponding imine, i