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Synthesis, Structure, and Thermolysis of a 1,5-Dioxa-4.lambda.5-phosphaspiro[3.3]heptane: A Novel Pentacoordinate 1,2-Oxaphosphetane

โœ Scribed by Kawashima, Takayuki; Takami, Hiromichi; Okazaki, Renji


Book ID
126988971
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
219 KB
Volume
116
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


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The first 1,5-dioxa-4l 4 -telluraspiro[3.3]heptane was synthesized and its structure was determined by X-ray analysis. This tellurane gave the corresponding oxirane and olefin, as well as alcohol, upon heating, which were shown to be formed via a radical pathway.

Synthesis, structure, and thermolysis of
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1,3,2l 5 -Oxazaphosphetidines bearing the Martin ligand were synthesized by the reaction of the corresponding iminophosphorane and carbonyl compounds and characterized by X-ray crystallographic analysis. Thermolysis of the oxazaphosphetidine gave the cyclic phosphinate and the corresponding imine, i