Synthesis, structure and substitution reactions of the binuclear phosphido-bridged complex
โ Scribed by Shin-Guang Shyu; Wen-Jin Wu; Yuh-Shang Wen; Shie-Ming Peng; Gene-Hsiang Lee
- Book ID
- 107812663
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 816 KB
- Volume
- 489
- Category
- Article
- ISSN
- 0022-328X
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The reaction of the ammonia diol [(NH,)4Rh(OH)2Rh(NH,),]4' with H,O, yields among other products a peroxo-bridged dimeric species [(NH,),Rh(O,)(OH) Rh(NH,),(H,O)](ClO,),. Its structure was determined by single-crystal X-ray diffraction. The crystals are monoclinic with space group P2,/n and lattice