Synthesis, structure and spectral properties of Mo(CO)(RC.tplbond.CR1)L2X2 complexes
โ Scribed by Winston, Paul B.; Burgmayer, Sharon J. Nieter; Templeton, Joseph L.
- Book ID
- 126047598
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 985 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0276-7333
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Quantum mechanical ab initio calculations at the MP2 and CCSD(T) level of theory have been used to investigate the geometries and bond energies of the complexes M(CO) 6ยฑx (H 2 ) x (M = Cr, Mo, W; x = 1, 2, 3). The theoretically predicted M(CO) 5 ยฑ(H 2 ) bond dissociation energies are in excellent ag
The triisocyanide ligand CH3C(CH2NC)3 reacts with Cr-acterized by an X-ray structure analysis allowing a direct com-(CO),(THF) depending on the stoichiometry to give the com-parison of the bonding parameters of coordinated and nonplexes CH3C(CH2NC),[CH2NC ~ Cr(C0)5]3-, (x = 1, 2). The coordinated is