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Synthesis, Structure, and Reactivity of Bridging Cyanide Complexes of the Formula [(η 5 -C 5 R 5 )Re(NO)(PPh 3 )CN(Ph 3 P)(ON)Re(η 5 -C 5 R‘ 5 )] + TfO - (R, R‘ = H, Me)

✍ Scribed by Stark, Gene A.; Arif, Atta M.; Gladysz, J. A.

Book ID
126110686
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
372 KB
Volume
16
Category
Article
ISSN
0276-7333

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📜 SIMILAR VOLUMES

Reactivity of the Inversely Polarised Ar
Reactivity of the Inversely Polarised Arsaalkenes R–As=C(NMe2)2 {R = [(η5-C5Me5)(CO)2Fe], tBuC(O)} Towards Vinylidene Complexes [η5-(C5H5)(CO)(NO)W=C=C(H)R] (R = Ph, tBu)
✍ Lothar Weber; Philipp Bayer; Gabriel Noveski; Hans-Georg Stammler; Beate Neumann 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 177 KB

## Abstract The reaction of the vinylidene complexes [(C~5~H~5~)(CO)(NO)W=C=C(H)R] (10a: R = __t__Bu; 10b: R = Ph) with the arsaalkene __t__BuC(O)–As=C(NMe~2~)~2~ (11) afforded the novel η^2^‐1‐arsaallene complexes [η^2^‐{__t__BuC(O)–As=C=C(H)R}W(CO)(NO)C~5~H~5~] (13: R = __t__Bu; 15: R = Ph). Simi