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Synthesis, structure and reactivity of .beta.-molybdenum dichloride

✍ Scribed by Beers, William W.; McCarley, Robert E.

Book ID
127085284
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
539 KB
Volume
24
Category
Article
ISSN
0020-1669

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Reactions of the complex [MoCl(eta(3)-C(3)H(4)-Me-2)(CO)(2)(phen)] (1) (phen=1,10-phenanthroline) with potassium arylamides were used to synthesize the amido complexes [Mo(N(R)Ar)(eta(3)-C(3)H(4)-Me-2)(CO)(2)(phen)] (R=H, Ar=Ph, 2 a; R=H, Ar=p-tolyl, 2 b; R=Me, Ar=Ph; 2 c). For 2 b the Mo-N(amido) b