Synthesis, reactivity, and molecular structure of cyclopentadienylmolybdenum dicarbonyl dimer. Molybdenum-molybdenum triple bond
β Scribed by Klingler, Robert J.; Butler, William; Curtis, M. David
- Book ID
- 126817974
- Publisher
- American Chemical Society
- Year
- 1975
- Tongue
- English
- Weight
- 252 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Reactions of the complex [MoCl(eta(3)-C(3)H(4)-Me-2)(CO)(2)(phen)] (1) (phen=1,10-phenanthroline) with potassium arylamides were used to synthesize the amido complexes [Mo(N(R)Ar)(eta(3)-C(3)H(4)-Me-2)(CO)(2)(phen)] (R=H, Ar=Ph, 2 a; R=H, Ar=p-tolyl, 2 b; R=Me, Ar=Ph; 2 c). For 2 b the Mo-N(amido) b
Telefax: Int. code + (617) 253-7030 e-mail: ccummins(cr rnit.edu [\*\*I This work was supported by a National Science Foundation CAREER award to C . C. C . (CHE-9501YY2) and by the MlTDepartmenl ofthemistry. Michael C(CD,),CH,), 33.36 (m. C(CD3)2CH3). 21.30 (4. IJIl'rU ( ' 6 H , M ~~2 ) : "P NMR