Synthesis, structure, and properties of a novel hydrated borate Rb4[B4O5(OH)4]2·3H2O
✍ Scribed by Yi Zhao; Shilie Pan; Feng Li; Yongjiang Wang; Xiaoyun Fan; Xiaoyu Dong; Dianzeng Jia; Jixi Guo; Zhongxiang Zhou
- Book ID
- 113914081
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- English
- Weight
- 856 KB
- Volume
- 13
- Category
- Article
- ISSN
- 1293-2558
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📜 SIMILAR VOLUMES
The crystal structure of synthetic Rb 2 [B 4 O 5 (OH) 4 ] ' 3.6H 2 O has been established from single-crystal X-ray di4raction data. It crystallizes in the orthorhombic space group Pbcn with a unit cell of dimensions a ؍ 11.276(5) A s , b ؍ 13.097(14) A s , c ؍ 16.751(5) A s ; V ؍ 2474(3) A
Large single crystals of the polar, hydrated pentaborates Me[B 5 O 6 (OH) 4 ]•2H 2 O (Me = Rb, NH 4 ) were grown from aqueous solutions. The structure of NH 4 [B 5 O 6 (OH) 4 ]•2H 2 O was redetermined and proved to be orthorhombic (space group Aba2 (No. 41) with a = 11.3192(7) Å, b = 11.0261(8) Å, c
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