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Synthesis, Structure, and Photophysical Properties of Novel Ruthenium(II) Carboxypyridine Type Complexes

✍ Scribed by Norrby, Thomas; Börje, Anna; Åkermark, Björn; Hammarström, Leif; Alsins, Jan; Lashgari, Kianosh; Norrestam, Rolf; Mårtensson, Jerker; Stenhagen, Gunnar


Book ID
120923925
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
327 KB
Volume
36
Category
Article
ISSN
0020-1669

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## Abstract The synthesis of a number of new 2,2′‐bipyridine ligands functionalized with bulky amino side groups is reported. Three homoleptic polypyridyl ruthenium (II) complexes, [Ru(L)~3~]^2+^ 2(PF~6~^−^), where L is 4,4′‐dioctylaminomethyl‐2,2′‐bipyridine (Ru4a), 4,4′‐didodecylaminomethyl‐2,2′‐