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Synthesis, Structure, and Ligand Redistribution Equilibria of Mixed Ligand Complexes of the Heavier Group 2 Elements Containing Pyrazolato andβ-Diketiminato Ligands

✍ Scribed by Hani M. El-Kaderi; Mary Jane Heeg; Charles H. Winter


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
176 KB
Volume
2005
Category
Article
ISSN
1434-1948

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The reaction of one equivalent of dilithiated O(SiMe 2 -Ap-H) 2 Cl(THF) Bu 4 N (5), O(SiMe 2 -Ap) 2 Y(BH 4 ) 2 Na(THF) 2 (6) and O(SiMe 2 -Ap) 2 Y(CH(TMS) 2 ) 2 Li(THF) 3 ( ), respectively. The [Ap-H = -N(2-amino-4-methylpyridine)] (1), generated in situ, with LnCl 3 (Ln = Y, Sm) in THF affords O(Si