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Synthesis, Structure and Electrochemistry of Macrocyclic Tetrametallic Group 6 (Fischer) Carbene Complexes

✍ Scribed by María P. López-Alberca; María J. Mancheño; Israel Fernández; Mar Gómez-Gallego; Miguel A. Sierra; Catherine Hemmert; Heinz Gornitzka

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
800 KB
Volume
2011
Category
Article
ISSN
1434-1948

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✍ Marta L. Lage; Israel Fernández; María J. Mancheño; Mar Gómez-Gallego; Miguel A. 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 482 KB 👁 2 views

## Abstract The UV spectra of Group 6 metal carbene complexes bearing a CpM(CO)~3~ (Cp=cyclopentadienyl) moiety bonded to the carbene carbon atom exhibit a redshift of the absorption maxima at higher wavelengths with respect to the parent monometallic complexes. This redshift is partly due to a hig