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The Noncarbonylative Photochemistry of Group 6 Fischer Carbene Complexes

✍ Scribed by Israel Fernández; Miguel A. Sierra; María José Mancheño; Mar Gómez-Gallego; Fernando P. Cossío

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
458 KB
Volume
2008
Category
Article
ISSN
1434-1948

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The Electronic Structure and Photochemis
The Electronic Structure and Photochemistry of Group 6 Bimetallic (Fischer) Carbene Complexes: Beyond the Photocarbonylation Reaction
✍ Marta L. Lage; Israel Fernández; María J. Mancheño; Mar Gómez-Gallego; Miguel A. 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 482 KB 👁 2 views

## Abstract The UV spectra of Group 6 metal carbene complexes bearing a CpM(CO)~3~ (Cp=cyclopentadienyl) moiety bonded to the carbene carbon atom exhibit a redshift of the absorption maxima at higher wavelengths with respect to the parent monometallic complexes. This redshift is partly due to a hig