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Synthesis, structure analysis, and stereochemistry of some reactions of cis- and trans-2,2,5-trimethyl-3-phenyl-1,3-oxaphospholane

✍ Scribed by Marsi, Kenneth L.; Co-Sarno, Maria Erlinda


Book ID
126869855
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
519 KB
Volume
42
Category
Article
ISSN
0022-3263

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Addition of dimethyl phosphonate to acetaldol gives a 3 : 7 mixture of diastereomeric dimethyl (1,3-dihydroxybutyl)phosphonates 3 and 4. The relative configurations at C-I and C-3 in these diols were established by the 13C NMR data of their 0-benzylidene derivatives. Axial preference-for the dimetho