Synthesis, Structural Evolution, and Electrical Properties of the Novel Mo 12 Cluster Compounds K 1+ x Mo 12 S 14 ( x = 0, 1.1, 1.3, and 1.6) with a Tunnel Structure
β Scribed by Picard, Soazig; Gougeon, Patrick; Potel, Michel
- Book ID
- 127016767
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 270 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
A new solid solution of general formula Bi(Bi 12Ψx Te x O 14 ) Mo 4Ψx V 1Ψx O 20 with x up to 2.5 has been prepared by simultaneous substitution of the couple Te 4Ψ -V 5Ψ for Bi 3Ψ -Mo 6Ψ in Bi 13 Mo 4 VO 34 . These materials have been studied by X-ray powder diffraction and thermal analysis, showin
normal Si-Si bond length has aroused much discussion as to the nature of the bonding between those Si a t o m ~. l ~\* ~~ The remarkable consistency observed for series I1 implies that: 1) the shortening of the Si..-Si distance in I2 is due mainly to the short Si-0 (1.66 A) BL compared to other BD's