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Synthesis, Structural Characterization, and Properties of a New Range of Strained 2-Aza[3]ferrocenophane Ligands: Dual Behavior as Electrochemical Sensors of Metal Ions or Anions

✍ Scribed by Tarraga, Alberto; Molina, Pedro; López, Juan Luis; Velasco, Maria D.; Bautista, Delia; Jones, Peter G.


Book ID
126023365
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
153 KB
Volume
21
Category
Article
ISSN
0276-7333

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Synthesis and electrochemical properties
✍ Alberto Tarraga; Pedro Molina; Juan Luis Lopez; Maria D Velasco 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 101 KB

The previously unreported 2-aza-[3]ferrocenophanes 3 and 4, prepared from a preformed [5]ferrocenophane, act as electrochemical sensors either of Mg 2+ , Zn 2+ and Ni 2+ cations (free ligand): a new redox peak appears in the CV shifted 310-360 mV or hydrogensulfate anion (protonated ligand) via a si