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Synthesis and electrochemical properties of a new range of strained 2-aza-[3]ferrocenophanes

✍ Scribed by Alberto Tarraga; Pedro Molina; Juan Luis Lopez; Maria D Velasco

Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 101 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)01969-4

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✦ Synopsis

The previously unreported 2-aza-[3]ferrocenophanes 3 and 4, prepared from a preformed [5]ferrocenophane, act as electrochemical sensors either of Mg 2+ , Zn 2+ and Ni 2+ cations (free ligand): a new redox peak appears in the CV shifted 310-360 mV or hydrogensulfate anion (protonated ligand) via a significant cathodic perturbation.

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