Synthesis, Structural Characterization, and Magnetic Properties of the Heteroleptic Dinuclear Nickel Selenite Complex [{Ni(TMEDA)SeO3}2]
✍ Scribed by Massimiliano Delferro; Claudia Graiff; Luciano Marchiò; Lisa Elviri; Marcello Mazzani; Mauro Riccò; Giovanni Predieri
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 544 KB
- Volume
- 2011
- Category
- Article
- ISSN
- 1434-1948
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## Abstract The tetranuclear nickel(II) complexes [(LNi^II^~2~)~2~(acetylenedicarboxylate)][BPh~4~]~2~ (2[BPh~4~]~2~), [(LNi^II^~2~)~2~(terephthalate)][BPh~4~]~2~ (3[BPh~4~]~2~), and [(LNi^II^~2~)~2~(isophthalate)][BPh~4~]~2~(4[BPh~4~]~2~), where L^2–^ represents a macrocyclic hexaaza‐dithiophenola
The new heteroleptic chromium complex [Ph 4 P][Cr(en)(S 5 ) 2 ] has been synthesised under mild solvothermal conditions by the reaction of chromium trichloride, sulfur, and tetraphenylphosphoniumbromide in a solution of ethylendiamine (en) in water. The crystal structure consists of isolated tetraph