The six-step synthesis of a chiral, pentadentate dihydrosalen ligand, carrying a mercaptomethyl group as additional binding site, is described. When this ligand was treated with nickel(I1) salts, a planar tetracoordinated nickel chelate was obtained, and not the expected pentacoordinated species. Th
✦ LIBER ✦
Synthesis, X-Ray Crystal Structure and Magnetic Characterization of the First “Ni3S4N3” Nickel Thiolate Cluster
✍ Scribed by Berkessel, Albrecht ;Bats, Jan W. ;Hüber, Martina ;Haase, Wolfgang ;Neumann, Thomas ;Seidel, Lutz
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1995
- Tongue
- English
- Weight
- 523 KB
- Volume
- 128
- Category
- Article
- ISSN
- 0009-2940
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