Synthesis, structural characterisation and reactivity of the d2 pseudo-metallocene complex Mo(N-2,6-iPr2C6H3)2(PMe3)2
✍ Scribed by Philip W. Dyer; Vernon C. Gibson; Judith A.K. Howard; Claire Wilson
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 286 KB
- Volume
- 462
- Category
- Article
- ISSN
- 0022-328X
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## Abstract [LiN(SiMe~3~)Ar]~2~ (1, Ar = 2,6‐__i__Pr~2~C~6~H~3~) is prepared by the reaction of HN(SiMe~3~)Ar with __n__BuLi in __n__‐hexane. This compound with an unusual structure contains a four‐membered [LiN]~2~ heterocycle with two solvent‐free two‐coordinate Li centers. Its molecular structur
## Abstract The very bulky phenols Ar\*OH (1) and Ar′OH (2), where Ar\* = C~6~H~3~‐2,6‐Trip~2~ (Trip = C~6~H~2~‐2,4,6‐__i__Pr~3~) and Ar′ = C~6~H~3~‐2,6‐Dipp~2~ (Dipp = C~6~H~3~‐2,6‐__i__Pr~2~), as well as their lithium and sodium derivatives (LiOAr\*)~2~ (3), (LiOAr′)~2~ (4) and (NaOAr\*)~2~ (5) h