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A Surprising Reaction of Trimethylphosphane with the Unsaturated Diruthenium Complex [(η6-C6Me6)2Ru2(μ2-H)3]+: Synthesis and Molecular Structure of the Cations [(η6-C6Me6)Ru2(PMe3)3(μ2-H)3]+ and [(η6-C6Me6)2Ru2(PMe3)2(μ2-H)(H)2]+

✍ Scribed by Mathieu J.-L. Tschan; Frédéric Chérioux; Bruno Therrien; Georg Süss-Fink


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
195 KB
Volume
2007
Category
Article
ISSN
1434-1948

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Reactions of Pt3Ru6(CO)2(μ3-H)(μ-H)3 wit
✍ Adams, Richard D. ;Barnard, Thomas S. ;Li, Zhaoyang ;Zhang, Lijuan 📂 Article 📅 1997 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 497 KB 👁 1 views

The reactions of [Pt3R~6(CO),l(p-H)3(p3-H)] (1) with PMe3 and PPh3 have produced the salts [Pt(PR3)3H]-[Pt3R~6(CO)2,(p3-H)(p-H)2]r 5a and 5d, R = Me and Ph in the yields 9% and 22%, respectively. By contrast the reaction of 1 with PPh, in the presence of Me3N0 has yielded the phosphane-substituted d