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Synthesis, structural analysis and evaluation of the catalytic activity of a non-symmetric N-(salicylidene)diethylenetriamine complex of copper(II)

✍ Scribed by HOSSEINI-MONFARED, Hassan; ALAVI, Sohaila; SICZEK, Milosz


Book ID
122502946
Publisher
Elsevier Science
Year
2013
Weight
597 KB
Volume
34
Category
Article
ISSN
1872-2067

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The reaction of 2 equiv of the optically active P, N bidentate ligands l-3 with RuC1,(PPh,)3 gives the RuCl,(l-3)2 (4-6) complexes in good yield as a mixture of isomers. The solid state structure of RuC1,( 2), (SC) is described: the two chlorine atoms are in tram position and due to steric crowding,