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Synthesis, spectroscopic, redox properties, and DNA cleavage activity of low-spin iron(III) complexes of bleomycin analogues

โœ Scribed by Hiromasa Kurosaki; Yoshinobu Ishikawa; Kentarou Hayashi; Miwako Sumi; Yoshiko Tanaka; Masafumi Goto; Kazufumi Inada; Isao Taniguchi; Mitsuhiko Shionoya; Hiroaki Matsuo; Masanori Sugiyama; Eiichi Kimura


Book ID
108331843
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
181 KB
Volume
294
Category
Article
ISSN
0020-1693

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โœ Junichi Nishijo; Nobuyuki Nishi ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 171 KB

## Abstract Highโ€temperature treatment of acetonitrile with CaC~2~ and FeCl~2~ afforded crystals of the new iron(III) __S__ = 1/2 lowโ€spin complexes [FeL~3~]ROH (R = CH~3~ or C~2~H~5~), whose crystal structures were determined by singleโ€crystal Xโ€ray structural analysis. The methanol complex consis