The two cobalt(III) complex salts [(CH 3 ) 4 N][trans-Co(NH 3 ) 2 (NO 2 ) 4 ] (I) and [(C 2 H 5 ) 4 N][trans-Co(NH 3 ) 2 (NO 2 ) 4 ] (II) have been synthesized in high yields by reacting equimolar quantities of [(CH 3 ) 4 N]Br and [(C 2 H 5 ) 4 N]Cl with K[trans-Co(NH 3 ) 2 (NO 2 ) 4 ], respectively
Synthesis, spectroscopic characterization and X-ray structure determination of tetrabutylammoniumtrans-diamminetetranitrocobaltate(III)
β Scribed by Raj Pal Sharma; Rajni Sharma; Ritu Bala; Dip Singh Gill; Sukhjinder Singh; Jugal Kishor Puri; Luca Russo; Kari Rissanen
- Publisher
- Springer
- Year
- 2006
- Tongue
- English
- Weight
- 242 KB
- Volume
- 36
- Category
- Article
- ISSN
- 1572-8854
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π SIMILAR VOLUMES
Dark maroon coloured single crystals of [cis-Co(en)2(N3)2][trans-Co(NH3)2(NO2)4] were obtained by slowly mixing the separately dissolved [cis-diazidobis(ethylenediamine)cobalt(III)] nitrate with potassium [trans-diamminetetranitrocobaltate(III)] in aqueous medium in 1:1 molar ratio. The complex salt
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