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Synthesis, Reactivity, and Fluxional Behaviour of [Ir2Rh2(CO)12], and Crystal Structure of [Ir2Rh2(CO)8(norbornadiene)2]

✍ Scribed by Giacomo Bondietti; Gianfranco Suardi; Renzo Ros; Raymond Roulet; Fabrizia Grepioni; Dario Braga


Publisher
John Wiley and Sons
Year
1993
Tongue
German
Weight
719 KB
Volume
76
Category
Article
ISSN
0018-019X

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Synthesis of [Ir3Rh(CO)12] and Fluxional
✍ Giacomo Bondietti; GΓ‘bor Laurenczy; Renzo Ros; Raymond Roulet πŸ“‚ Article πŸ“… 1994 πŸ› John Wiley and Sons 🌐 German βš– 1007 KB

## Abstract The redox condensation of [Ir(CO)~4~]^–^, [Ir(cod)(THF)~2~]^+^, and [Rh(cod)(THF)~2~]^+^ (cod = cycloocta‐1,5‐diene) followed by saturation with CO (1 atm) in THF afforded the first synthetic route to pure [Ir~3~Rh(CO)~12~] (1). Substitution of CO by monodentate ligands gave [Ir~3~Rh(CO