Synthesis of [Ir3Rh(CO)12] and Fluxional
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Giacomo Bondietti; GΓ‘bor Laurenczy; Renzo Ros; Raymond Roulet
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Article
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1994
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John Wiley and Sons
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German
β 1007 KB
## Abstract The redox condensation of [Ir(CO)~4~]^β^, [Ir(cod)(THF)~2~]^+^, and [Rh(cod)(THF)~2~]^+^ (cod = cyclooctaβ1,5βdiene) followed by saturation with CO (1 atm) in THF afforded the first synthetic route to pure [Ir~3~Rh(CO)~12~] (1). Substitution of CO by monodentate ligands gave [Ir~3~Rh(CO